Material Safety Data Sheet
L(-)-Borneol, 98%
ACC# 33824
Section 1 - Chemical Product and Company Identification
*MSDS Name:* L(-)-Borneol, 98%
*Catalog Numbers:* AC160650000, AC160651000, AC160655000 *
Synonyms:* endo-(1S)-1,7,7-Trimethylbicyclo[2.2.1]heptan-2-ol;
(-)-Borneol; (1S-Endo)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-ol;
1-Bornyl alcohol; Bicyclo(2.2.1)heptan-2-ol, 1,7,7-trimethyl-,
(1S-endo)-; Bicyclo[2.2.1]heptan-2-ol, 1,7,7-trimethyl-, (1-endo)-;
Bicyclo[2.2.1]heptan-2-ol, 1,7,7-trimethyl-, (1S,2R,4S)-; Borneol,
(1S,2R,4S)-(-)-; l-2-Bornanol; l-2-Camphanol *
Company Identification:*
Acros Organics N.V.
One Reagent Lane
Fair Lawn, NJ 07410
*For information in North America, call:* 800-ACROS-01
*For emergencies in the US, call CHEMTREC:* 800-424-9300
Section 2 - Composition, Information on Ingredients
*CAS#* *Chemical Name* *Percent* *EINECS/ELINCS*
464-45-9 L(-)-Borneol 98 207-353-1
*
Hazard Symbols:* None listed. *
Risk Phrases:* None listed.
Section 3 - Hazards Identification
*EMERGENCY OVERVIEW*
Appearance: white crystalline powder. Flash Point: 65 deg C. * Warning!*
Flammable solid. May cause central nervous system effects. May cause
sensitization by skin contact. May cause eye and skin irritation. May
cause respiratory and digestive tract irritation.
*Target Organs: *Central nervous system.
*Potential Health Effects*
*Eye:* May cause eye irritation. May cause chemical conjunctivitis and
corneal damage.
*Skin:* May cause mild skin irritation.
*Ingestion:* May cause central nervous system depression. May cause
nausea, vomiting, abdominal pain, and increased salivation.
*Inhalation:* May cause respiratory tract irritation. Olfactory fatigue
may occur. Can produce delayed pulmonary edema.
*Chronic:* No information found.
Section 4 - First Aid Measures
*Eyes:* Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
*Skin:* Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
*Ingestion:* Never give anything by mouth to an unconscious person. Get
medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth
and drink 2-4 cupfuls of milk or water.
*Inhalation:* Remove from exposure and move to fresh air immediately. If
not breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
*Notes to Physician:* Treat symptomatically and supportively.
Section 5 - Fire Fighting Measures
*General Information:* As in any fire, wear a self-contained breathing
apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and
full protective gear. Will burn if involved in a fire. Dust can be an
explosion hazard when exposed to heat or flame. Flammable solid. May
burn rapidly with flare burning effect. May re-ignite after fire is
extinguished.
*Extinguishing Media:* For large fires, use water spray, fog or regular
foam. Contact professional fire-fighters immediately. For small fires,
use dry chemical, carbon dioxide, sand, earth, water spray or regular
foam. Cool containers with flooding quantities of water until well after
fire is out.
*Flash Point:* 65 deg C ( 149.00 deg F)
*Autoignition Temperature:* Not applicable.
*Explosion Limits, Lower:*Not available.
* Upper:* Not available.
*NFPA Rating:* (estimated) Health: 1; Flammability: 2; Instability: 0
Section 6 - Accidental Release Measures
*General Information:* Use proper personal protective equipment as
indicated in Section 8.
*Spills/Leaks:* Vacuum or sweep up material and place into a suitable
disposal container. Scoop up with a nonsparking tool, then place into a
suitable container for disposal. Avoid generating dusty conditions.
Remove all sources of ignition.
Section 7 - Handling and Storage
*Handling:* Minimize dust generation and accumulation. Avoid contact
with skin and eyes. Empty containers retain product residue, (liquid
and/or vapor), and can be dangerous. Avoid contact with heat, sparks and
flame. Use only in a chemical fume hood. Do not pressurize, cut, weld,
braze, solder, drill, grind, or expose empty containers to heat, sparks
or open flames.
*Storage:* Keep away from heat, sparks, and flame. Keep away from
sources of ignition. Store in a tightly closed container.
Flammables-area. Store in a cool, dry area away from incompatible
substances.
Section 8 - Exposure Controls, Personal Protection
*Engineering Controls:* Facilities storing or utilizing this material
should be equipped with an eyewash facility and a safety shower. Use
adequate general or local explosion-proof ventilation to keep airborne
levels to acceptable levels.
*Exposure Limits*
*Chemical Name* *ACGIH* *NIOSH* *OSHA - Final PELs*
L(-)-Borneol none listed none listed none listed
*OSHA Vacated PELs:* L(-)-Borneol: No OSHA Vacated PELs are listed for
this chemical.
*Personal Protective Equipment*
*Eyes:* Wear appropriate protective eyeglasses or chemical safety
goggles as described by OSHA's eye and face protection regulations in 29
CFR 1910.133 or European Standard EN166.
*Skin:* Wear appropriate protective gloves to prevent skin exposure.
*Clothing:* Wear appropriate protective clothing to prevent skin exposure.
*Respirators:* A respiratory protection program that meets OSHA's 29 CFR
1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be
followed whenever workplace conditions warrant a respirator's use.
Section 9 - Physical and Chemical Properties
*Physical State:* Crystalline powder
*Appearance:* white
*Odor:* none reported
*pH:* Not available.
*Vapor Pressure:* 33.5 mm Hg @ 25 deg C
*Vapor Density:* 5.31
*Evaporation Rate:*Not available.
*Viscosity:* Not available.
*Boiling Point:* 210 deg C
*Freezing/Melting Point:*207 - 208 deg C
*Decomposition Temperature:*Not available.
*Solubility:* insoluble
*Specific Gravity/Density:*Not available.
*Molecular Formula:*C10H18O
*Molecular Weight:*154.25
Section 10 - Stability and Reactivity
*Chemical Stability:* Stable at room temperature in closed containers
under normal storage and handling conditions.
*Conditions to Avoid:* Incompatible materials, ignition sources, dust
generation, excess heat.
*Incompatibilities with Other Materials:* Strong oxidizing agents.
*Hazardous Decomposition Products:* Carbon monoxide, irritating and
toxic fumes and gases, carbon dioxide.
*Hazardous Polymerization:* Has not been reported.
Section 11 - Toxicological Information
*RTECS#:*
*CAS#* 464-45-9: DT5095000
*LD50/LC50:*
CAS# 464-45-9:
Draize test, rabbit, skin: 500 mg/24H Mild;
Oral, rat: LD50 = 5800 mg/kg;
*Carcinogenicity:*
CAS# 464-45-9: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
*Epidemiology:* No information found.
*Teratogenicity:* No information found.
*Reproductive Effects:* No information found.
*Neurotoxicity:* No information found.
*Mutagenicity:* No information found.
*Other Studies:* Standard Draize Test: Administration onto the skin
(rabbit) = 500 mg/24H (Mild).
Section 12 - Ecological Information
No information available.
Section 13 - Disposal Considerations
Chemical waste generators must determine whether a discarded chemical is
classified as a hazardous waste. US EPA guidelines for the
classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous
waste regulations to ensure complete and accurate classification.
*RCRA P-Series:* None listed.
*RCRA U-Series:* None listed.
Section 14 - Transport Information
* * *US DOT* *IATA* *RID/ADR* *IMO* *Canada TDG*
*Shipping Name:* BORNEOL No information available.
*Hazard Class:* 4.1
*UN Number:* UN1312
*Packing Group:* III
Section 15 - Regulatory Information
*US FEDERAL**
*
*TSCA*
CAS# 464-45-9 is listed on the TSCA inventory.
*Health & Safety Reporting List*
None of the chemicals are on the Health & Safety Reporting List.
*Chemical Test Rules*
None of the chemicals in this product are under a Chemical Test Rule.
*Section 12b*
None of the chemicals are listed under TSCA Section 12b.
*TSCA Significant New Use Rule*
None of the chemicals in this material have a SNUR under TSCA.
*SARA*
*CERCLA Hazardous Substances and corresponding RQs*
None of the chemicals in this material have an RQ.
*SARA Section 302 Extremely Hazardous Substances*
None of the chemicals in this product have a TPQ.
*Section 313*
No chemicals are reportable under Section 313.
*Clean Air Act:*
This material does not contain any hazardous air pollutants. This
material does not contain any Class 1 Ozone depletors. This material
does not contain any Class 2 Ozone depletors.
*Clean Water Act:*
None of the chemicals in this product are listed as Hazardous Substances
under the CWA. None of the chemicals in this product are listed as
Priority Pollutants under the CWA. None of the chemicals in this product
are listed as Toxic Pollutants under the CWA.
*OSHA:*
None of the chemicals in this product are considered highly hazardous by
OSHA.
*STATE*
CAS# 464-45-9 is not present on state lists from CA, PA, MN, MA, FL, or NJ.
California No Significant Risk Level: None of the chemicals in this
product are listed. *
European/International Regulations*
*European Labeling in Accordance with EC Directives*
*Hazard Symbols:*
Not available. *
Risk Phrases:*
*
Safety Phrases:*
S 24/25 Avoid contact with skin and eyes.
*
WGK (Water Danger/Protection)*
CAS# 464-45-9: No information available.
*Canada - DSL/NDSL*
CAS# 464-45-9 is listed on Canada's DSL List.
*Canada - WHMIS*
This product has a WHMIS classification of B4, D2B.
*Canadian Ingredient Disclosure List*
*Exposure Limits*
Section 16 - Additional Information
*MSDS Creation Date:* 9/02/1997
*Revision #4 Date:* 3/18/2003
/
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect
to such information, and we assume no liability resulting from its use.
Users should make their own investigations to determine the suitability
of the information for their particular purposes. In no event shall
Fisher be liable for any claims, losses, or damages of any third party
or for lost profits or any special, indirect, incidental, consequential
or exemplary damages, howsoever arising, even if Fisher has been advised
of the possibility of such damages. /